Not really. There’s not many 2k topcoats that will work as an IMC, most will delaminate as soon as you flex or try to trim the part. Some do work for whatever reason, though this requires experimentation and nobody can say how long it will last for. Also, because you are using a polyester infusion resin, you also have the high potential of the resin attacking the 2k coating when you infuse. 2k polyurethanes tend to be quite vulnerable to styrene attack until they are well cured. But the better cured the coating is, the poorer adhesion you will get without doing surface prep. Unfortunately this is one of those subjects that nobody can really give a definitive answer on because if you aren’t using a product that was developed specifically for the purpose, then it’s all an experiment. There’s too many different chemicals at play to say how it will work.
And, no matter what coating you use it will only come out as shiny as your mould surface.