Yeh it can be tricky, I do think there is a bit of an art to sanding and compounding. I’ve by no means mastered it, but I have had better results and worse results and I try to just repeat what works.
I only use semi-permanent release systems, no wax. PVA I used to use to make moulds, but I always sprayed that. I would definitely advise spraying it if you can, it’s infinitely better than brushing or wiping it.
Using glass can be tricky, as a lot of release waxes don’t actually work on glass due to how slick it is. What happens is you apply the wax, and then when you buff it off it actually comes off entirely and none stays on the surface. I do however know for a fact that TR-108 release wax works on glass, and works well with PVA. I would always recommend using a chemical release agent on glass though, much much better system.