Do a search on “free standing postcure”.
First of all I am a bit surprised you are not able to source some high temperature resistant moulding material. Most polyester companies carry these materials, and usually are temperature resistant up to 80 degrees or so. I have worked with Reichhold, Nord and Scott Bader, which all work fine.
Once postcured inmould up to 80 degrees, there is usually not a big problem to postcure to 100 degrees freestanding. As long as you are able to control the temperature in your oven. I would suggest buying a PID controller for that, and a fan or 2 to mix the air in the oven. Make sure you control your ramp temperature. Ask your resin supplier for a maximum ramp. If not known, use 3 degrees / hour, which is very conservative. (so ramp to 80 degrees fast (20 degrees per hour, as that should be possible anyhow, then change to 3 degrees per hour until 100 degrees is reached. Keep it there for the prescribed amount of time.)