Way, way, way back in the day I successfully used Krylon rattle can paint on a plug. I let it dry for 4 or 5 days, used wax and PVA, and it released just fine. Krylon has since changed their chemistry so I don’t know if it still works. You cannot use a solvent based semi-perm release system, or wax alone, on a rattle can paint. Even single component auto paints that get shot from gun don’t work. If you want to use a semi you need to use a 2-part catalyzed paint or primer.
BTW, testing any unknown resin, release agent, and release surface (paint) isn’t a waste of time. It usually will save you lots of time, materials, and heart-ache. Newbies rarely test and pay dearly for it. Experienced fabricators will test any new combination to them. I would also rather test a combination myself than read about one on the internet. Each aspect of the combination is important (plug paint, release system, molding resins). Someone may recommend a plug paint that works with their molding resin and release but may not work with your chosen resins and release. Some resins don’t work with semi-permanent releases. Some plugs paints will release with just wax and polyester resin but stick with epoxy based resins. You can have a great releasing mold and switch the layup resin and have sticking either due to the release agent or the release surface incompatibility. TEST! TEST! TEST!