What he told was that the peelply helped creating a sort of fair surface, with a texture which helps secondary bonding.
And that is about the ONLY function of peelply: create a textured surface for secondary bonding.
But let’s take one step back. What kind of structure are you trying to make? I understand it has something to do with bodywork. (of a car?)
If it is one-off construction, consider the following:
-CNC route a negative mould, in a hard foam. Vacuum a flexible vacuum film, such as SL200 or a PVA film into the mould. This is your mould surface. PVA needs no waxing, SL200 could benefit from a coat of wax or PVA.
In this mould (keep the vacuum) you can create your bodywork. It does need some sanding afterwards, depending on the foam, but for the rest it is clean, cheap, simple.
The laminate stack for your part would be:
laminate
peelply on areas where there is secondary bonding
perforated film (P3 or P31 perforated, not too much perfs)
bleeder
vacuum film
Pull about 15 Hg vacuum.
This is a nice starting point.