I allways use CSM when making moulds with a styrene based resins, its cheap and easier to consolidate (I find).
The skin layer is the first fibreglass layer after the gelcoat. Its not necessary but it prevents print through from the reinforcement layers that follow. Usually it is a lightweight layer of glass, so that it can conform to corners easier, but also so that it doesn’t print through itself. Its usually VE so that it makes a good bond with the gelcoat, but also acts as a latch for the polyester, as its a bit runnier and its styrene levels will be higher than the gelcoat.
Here’s an example:
Gel (GC206):
Skin (AOC):
Reinforcement (Optimold):
The first couple of moulds I made were scrap, as I didnt consolidate the skin enough and I got air entrapment in the corners. It wasnt obvious at first, but once heated, the pockets blistered.
Make sure you are working at least at 20 degrees C.
The other thing I recommend is to have your reinforcement layers cut and ready to go. Each manufacturer is different (Neomold is 4x450g, Optimold is 5x450g), and have your resin for each layer weighed and ready to be catalyzed in its own cup. The amount of resin will seem like alot, (between 3-4 parts resin to 1 part matt), but it has to go on there, otherwise it wont exotherm. And on the back of exotherming, you need to work fast. Make sure you measure the catalyst accordingly so that you have enough time to finish before it starts to heat up.
If you use RM3000 like herman recommended, you dont have to worry about exotherms or thickness, but its a VE based tooling resin and will be more expensive.
Optimold is good for 100C. Neomould says its Tg if 80, but Ive taken it to 100 consistently. For a bonnet, you’ll want to have a pretty thick mould, so 2 runs of Optimold will work. Unless youre only doing one part, in which case I would only do 1 run.