someone please correct me if I dont get this…
Most epoxy has a amine blush on the surface when it cures, the amine blush will not let the PER or gelcoat cure where it is in contact. You can sand off the blush (when the part is fully cured) and spray a poly product on it BUT you get no chemical bond from the part to the poly topcoat.
I did a piece to play with Duratec one time and I didn’t sand the part very well before I sprayed it. It looked good and I was happy untill I wet sanded it and as I did I noticed a white spot, it was the Duratec coming off the part, I chiped a small area and blew a air hose on it, in about 5 min I blew off all the Duratec from the part.
There is stuff like SB-112 that PE can be sprayed on but SB-112 has a short pot life, is rather thick and high $(stuff I have is anyway)
so as for me no chemical bond for poly is bad. just my $.02