Hey Burrito,
I am no expert in this, but just a few things to consider:
Is this going to be a one-off part? Or are you planning to make a few different plugs/moulds/etc.?
The reason I ask is that I recently looked into using Duratec surfacing primer for my own project, but it turns out it’s quite expensive. Way over my limited DIY budget and I believe you have to buy it in large quantities.
From what I have read here I learnt that 2 pack paints will be more of a sure bet, you can polish them to a high gloss finish and the surface is hard so it makes a good finish for your plug. (But again, there are so many different materials out there, so you should always test when using new products. That seems to be the key to avoid lots of problems.)
Definitely looks like at least a two piece mould would be needed. Hard to say exactly without seeing the part. You just need to check that there won’t be any undercuts that get caught…
A suggestion if this is your first time working with composites - you might like to do some simple test pieces first before attempting this plug/mould. This will just help you become familiar with the materials you’re using, which IMO goes a long way towards avoiding problems.
Especially if you are expecting that you will have any trouble releasing the plug from the mould… I know it’s tempting to think that way, more so if it’s a one-off job, but if you have problems with that, you will most likely end up with defects on your mould… better to do test parts, then do the real part properly.
Hope that helps! There is a bunch of information on the forums here, keep having a search around, keep reading, you can definitely learn a lot here!