There are two different ways that i usually build plugs.
One is with sheets of mdf (thin mdf can be curved gently) be sure you use plenty of stiffening ribs inside tho to stop it flexing and build it on a good solid base. Body filler edges and corners. Will need painting to get a good smooth surface. 2K primer works well and can be flat and polished good snough for most items.
The other way to make plugs is to cut ribs to shape at say 4 inch spacings, fill the gaps with foam. Sand to shape (using the ribs as a guild to the shape). Once happy with the shape cover with grp (if polyester resin is used make sure is compatable with the foam and wont melt it). Sand the high areas. Cover in filler. Once happy with the shape it will again need painting. 2K primer will work again.
The second method is usually better if you require a 3d shape that is quite complex.
Remember the better the finish on your plug the better your parts will be. Make sure you are happy with your shapping and get someone else to come and be critical about your shaping and surface finish! You will be thankfull later