I use duratec in-mold as well, and I spray it with a 2.0mm HVLP. The thickness you have to spray and the method of spraying is counterintuitive.
First off forget mist coats. I had the same alligation problems and it’s because I treated Duratec like it was paint (hard to not do when you are a bodyman by trade ;)).
Anyways you have to treat duratec like thinned out, sprayable bondo (which it is chemically more akin to). Flow on a heavy coat. Make sure the fluid needle screw is all the way out, and keep the fan control fairly narrow, narrower than you would spray paint with- probably a 6" fan at an 8" distance away from the part. Flow it on in long, continuous stripes, do not sweep back and forth. You should be flowing enough on that it gets wet and shiny and ready to start making runs. You will definietly use a lot of material, but duratec assumes you are using the product because of its build properties.
Also, I’ve never had great luck doing layups with the duratec stick slightly tacky. It seems far less prone to lift if you give it a good two hours to cure.
It will not form as good of a bond as unwaxed gelcoat might, but it certainly isn’t a waxed product that will resist adhesion either, and I have not heard of anyone having problems with duratec delaminating from parts that were laid up on cured duratec.
Sorry of you knew all of this, but I had similar problems so thought I’d relay what I found. I’ll probably try gelcoat at some point, but duratec is really nice to work with once you get it down. And yeah when spraying multiple cupfulls be certain not to overcatalyze.
For something like a front bumper skin that might need 2 or 3 full cups, I tend to catalyze each cup a little more. Something like 1%, 1.5%, 2.0%. I suppose that might be bad practice but it tends to actually mean that by the time one coat is sprayed and the solvents flash, it’s sortof “on the same page” as the next, more catalyed coat. And the residue in you gun won’t go rock hard while you re-fill the cup. 